We know that $[Ni(CO)_4]$ $=$ $0.85$ M at the equilibrium:
$Ni(s)$ $+$ $4CO(g)$ $Ni(CO)_4(g)$, with $K$ $=$ $5.0\cdot10^4 $ $M^{-1}$
So: $K = $
..........
from where we get $[CO]$:
..........
Concentration c expressed in $\frac{g}{L}$:
Mass of $CO$ in $1$ L =
..........
$c_{CO}$ $=$ ..........
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