In a chemical species the charges are determined from → Lewis structures of atoms. Method: The two electrons of each bond are distributed equally between the two atoms they connect, then we compare them to the Lewis structure. For example:
Attribution of the electrons:
Comparison with Lewis structures:
Correct charges:
If the dative bonds are represented by arrows, we write only the global charge by exposing it behind the molecule . For example: p>
Dative bonds (the red electrons are "supplied" only by the chlorine pairs):
Attribution of the electrons:
Correct charges:
Dative bonds represented by arrows (two - charges and two + charges omitted):
This mode of representation is to be discouraged in the study of the mechanisms, since it conceals the real charges!