Determination of the molecular formula of alcohols
Exercise 2
An organic compound of molar mass $58 \; \frac{g}{mol}$ contains the elements $C, H $ and $ O $
Elemental analysis gave the following percentages:
$ C: \: $ 62.1%
$ H: \: $ 10.3%
1) Determine the molecular formula!
2) If it would be an alcohol, what can you say about its hydrocarbon chain?
1)
General formula:
$C_xH_yO_z$
$\%_C$ $=$ $62.1$
$\frac{x\cdot 12}{58}$ $=$ $0.621$
$x$ $\approx$ $3$
$\%_H$ $=$ $10.3$
$\frac{y\cdot 1}{58}$ $=$ $0.103$
$y$ $\approx$ $6$
$\%_O$ $=$ $100-62.1-10.3$ $=$ $27.6$
$\frac{z\cdot 16}{58}$ $=$ $0.276$
$z$ $\approx$ $ 1$
Molecular formula:
$C_3H_6O$
2)
The molecular formula has the general type :
$C_nH_{2n}O$
Beeing an alcohol (no $C = O$), the chain must be either cyclic or aliphatic with one double bond.