Magnesium sulfate
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1. Potassium hydroxide |
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$Mg^{2+}$ $+$ $2OH^-$ $\longrightarrow$ $Mg(OH)_2$ - white gelatinous precipitate - soluble in dilute mineral acids |
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2. Ammonia |
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$Mg^{2+}$ $+$ $2OH^-$ $\longrightarrow$ $Mg(OH)_2$ - Precipitation less complete than with $KOH$ - The presence of $NH_4Cl$ in sufficient qty inhibits precipitation |
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3. Ammonium carbonate |
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$Mg^{2+}$ $+$ $CO_3^{2-}$ $\longrightarrow$ $MgCO_3$ - White crystalline precipitate - Soluble in dilute mineral acids - The presence of $NH_4Cl$ in sufficient qty inhibits this precipitation, and that allows to precipitate the alkaline earth carbonates excluding $MgCO_3$ |
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4. Sodium hydrogenophsphate in the presence of $NH_3$/$NH_4Cl$ |
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$Mg^{2+}$ $+$ $NH_3$ $+HPO_4^{2-}$ $\longrightarrow$ $MgNH_4PO_4$ - White crystalline precipitate - soluble in HCl $ $ - soluble in acetic acid - Possibly rub |
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5. Magneson II (p-nitrobenzene-azo-α-naphtol) |
- In the presence of $Mg^{2 +}$, the strongly alkaline solution of reagent turns red-purple to azure blue. |
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5. Thiazole yellow |
- In the presence of $Mg^{2+}$, the strongly alkaline solution of reagent turns from yellow-orange to flame-red . |
Solubilities (in g/100mL)