The compounds

Definition

A compound is a chemical substance whose molecules (or lattices) are made out of several kinds of atoms.

 

Examples

ModelFormulaName 
$H_2O$water
$CO_2$carbon dioxyde
$C_4H_{10}$butane

Valence

The oxygen atom makes 2 bonds (it is bound in 2 "places"): it has valence 2. One hydrogen atom H (f.i. the right one) makes only one bond : it has valence 1.

Each atom has one main valence:

Formulas

Often valences allow to foresee the formulas of compounds: Think about atoms being Lego blocks whose sizes would correspond to their valences and build a molecule like a straight wall:

Valences of atom groups

Bigger molecules contain often the same atom groups (wrongly called "radicals") to which can be assigned valences, for instance for the hydroxide group OH :

NomGroupeValence 
Hydoxide $OH$1
Nitrite $NO_2$1
Nitrate $NO_3$1
Carbonate $CO_3$2
Sulfite $SO_3$2
Sulfate $SO_4$2
Phosphate $PO_4$3
Ammonium $NH_4$1

Think now about groups being also Lego blocks whose sizes would correspond to their valences and use the method of the "straight wall" to find the formulas of their compounds, f.i.: $NaOH$ $NH_4I$ A$l(NO_2)_3$ $NH_4NO_3$ $BPO_4$ $H_2SO_4$ $(NH_4)_3PO_4$ A$l(OH)_3$ $(NH_4)_2S$ $H_2CO_3$ $HNO_3$ $Ca_2(PO_4)_3$

Names

The name of compound formed by two atoms or groups X and Y has 3 different parts:

Y X Suffixe 
sodiumbromide
ammoniumchloride
magnesiumsulfide
aluminiumcarbonate
 

 

- X is the name of the atom situated higher and more to the right side in the periodic table. Its name suffix is often ide Special cases: O : Oxide ; S : sulfide; N: nitride; P: phosphide; C: carbide - Y is the normal name of the atom situated lower and more to the left side in the periodic table. - The groups, except ammonium, occupy the place of X in these names. Examples:

  
$Ca$$O$    :  calcium oxide 
$Mg$$I_2$    :  magnesium iodide 
$NH_4$$Cl$    :  ammonium chloride 
$Na_3$$PO_4$    :  sodium phosphate 
$Sr$$(OH)_2$    :  strontium hydroxide 
A$l_2$$(SO_3)_3$    :  aluminium sulfite  

The acids

The acids are compounds from hydrogen with nonmetals or groups Examples: $HCl$; $H_2SO_4$; $H_2CO_3$ Exceptions: $H_2O$: water ; $NH_3$: ammonia; $PH_3$: phosphine; $CH_4$: methane

Acids have special names according to the rule :

hydrogen (..)ide $\longrightarrow$(..)hydric acid
hydrogen (..)ite $\longrightarrow$(..)ous acid
hydrogen (..)ate $\longrightarrow$(..)ic acid
 

for instance:

hydrogen chloride $\longrightarrow$chlorhydric acid
hydrogen sulfite $\longrightarrow$sulfurous acid
hydrogen phoshate $\longrightarrow$phosphoric acid

Some little corrections are made for euphonious reasons !

The hydrogen salts

The hydrogen salts contain hydrogenated groups whose names are for instance:

Groups or atoms with valence 2 :

group+H    nom  valence 
HShydrogen sulfide   1
HSO3hydrogen sulfite   1
HSO4hydrogen sulfate   1
HCO3hydrogen carbonate   1

Groups or atoms with valence 3 :

group+xH    nom  valence 
  HPO4hydrogen phosphate   2
  H2PO4dihydrogen phosphate   1

The addition of one H reduces the valence by one unit !

So we find the names of hydrogenated salts:

Mg(HS)2 magnesium hydrogen sulfide
LiHSO3lithium hydrogen sulfite
NaH2PO4sodium dihydrogen phosphate
Al2(HPO4)3aluminium hydrogen phosphate