Theory of acids and bases

pH of acids

Exercise 17

    

 

You dispose of a $0.200\;M$ solution of $H_3C_6H_5O_7$ (citric acid, $K_a$ $=$ $3.5\cdot 10^{-4}$) Equilibrium of hydrolysis: $H_3C_6H_5O_7$ $+$ $H_2O$ $H_3O^+$ $+$ $H_2C_6H_5O_7^-$

What are the changes in concentration of each species?

a) $+x\;M$, $-x\;M$, $+x\;M$ b) $-x\;M$, $+x\;M$, $+x\;M$ c) $+x\;M$, $+x\;M$, $+x\;M$ d) $-x\;M$, $+x\;M$, $-x\;M$

The answer b) is correct, because when one mole of acid dissociates, one mole of each ion appears.