$2{S_2}O_3^{2-}$ $..$ $\longrightarrow$ $S_4O_6^{2-}$ $..$ (Tetrathionate is produced) The oxidation nuber of (S) varies from 2 to $\frac{5}{2}$, therefore, the oxidation number $2\cdot 2\cdot 2 = 8$ of all the $S$ atoms of $2S_2O_3^{2-}$ goes up to the oxidation number $4\cdot \frac{5}{2} = 10$ of all the $S$ atoms of $S_4O_6^{2-}$, so $2e^-$ are lost: $2S_2O_3^{2-}$ $-$ $2e^-$ $\longrightarrow$ $S_4O_6^{2-}$ Now the complete equation: $2S_2O_3^{2-}$ $-$ $2e^-$ $\longrightarrow$ $S_4O_6^{2-}$ $I_2$ $+$ $2e^-$ $\longrightarrow$ $2I^-$ $2S_2O_3^{2-}$ $+$ $I_2$ $\longrightarrow$ $S_4O_6^{2-}$ $+$ $2I^-$