Experiment: Copper(II) sulfate and ammonia - Strong and weak ligand -

Ammonia gas ( $NH_3$ ) releases in water the hydroxyde ion. Write the equation of this equilibrium.

$NH_3$ $+$ $H_2O$$ NH_4^+$ $+$ $OH^-$

In water, what state is the copper(II) ion in?

$[Cu(H_2O)_5]^{2+}$

In tubes 2 et 3 a precipitate appears. Which one?

$Cu^{2+}(OH^-)_2$ , copper(II) hydroxide

Write the equation of this precipitation taking account of the real initial state of the copper(II) ion.

$[Cu(H_2O)_5]^{2+}$ $+2OH^-$ $\rightarrow$ $Cu^{2+}(OH^-)_2$ $+$ $5H_2O$

In the test tube 4 an dark blue colour appears. It is due to the complex ion tetramminecopper(II). Write the formula of that solution.

$[Cu(NH_3)_4]^{2+}$ $+$ $SO_4^{2-}$

Write the equation of the formation of this solution starting with the precipitate of test tubes 2 and 3.

$Cu^{2+}(OH^-)_2$ $+$ $4NH_3$ $\rightarrow$ $[Cu(NH_3)_4]^{2+}$ $+$ $2OH^-$